History of Superconductivity and Superfluidity

The history of physics from ancient times to the modern day, focusing on light and matter. The Pauli exclusion principle means that sometimes electrons can move without resistance. Superconductivity occurs when this causes an electric field. This also creates a force that expels magnetic fields, causing objects to levitate. Superfluids work in a similar way, and allows water to flow upwards.

Last updated on 5th August 2017 by Dr Helen Klus

1. Discovery of superconductivity

Superconductivity is a macroscopic quantum effect that was first discovered by Dutch physicist Heike Kamerlingh Onnes in 1911[1]. Kamerlingh Onnes was studying the electrical resistance of mercury at low temperatures and found that at about 2 Kelvin (-267.15 °C) the resistance abruptly dropped to zero.

In ordinary conductors, electrical resistance lowers as the temperature decreases but it never reaches zero because the electrons collide with each other. Yet an electric current flowing in a loop of mercury wire could potentially maintain a current forever, with no applied voltage - although you would have to provide the energy to keep it cool - and so mercury was dubbed a superconductor.

1.1 The Meissner effect

Many other metals were found to act the same way and, in 1933, German physicists Walther Meissner and Robert Ochsenfeld showed that superconductors also expel magnetic fields[2]. This is known as the Meissner effect. The force of a superconductor's magnetic field can be stronger than the gravitational force of some objects, allowing them to levitate.

Photograph of a levitating tile.

A ceramic tile levitating over a superconductor's magnetic field. Image credit: Garrett Pennell/CC-SA.

1.2 Cooper pairs

In 1957, American physicists John Bardeen, Leon Cooper, and John Robert Schrieffer showed that superconductivity can be explained if, at low enough energies, electrons form a single quantum wave made of pairs of electrons with equal and opposite spins and momentums[3][4]. These are known as pair condensates, or Cooper pairs.

Electrons are normally repulsed by the negative charge of other electrons but, in 1956, Cooper had shown that sometimes electrons can overcome this repulsion and form bound pairs[5]. This happens when a stronger force attracts both electrons.

In classical theories, this could be the charge of the positive ions within a conductive metal, but in the quantum case, this occurs due to the interaction of electrons with phonons. A phonon is the unit of energy that arises because the atoms within a metal are oscillating. These oscillations produce waves that carry heat and sound throughout the metal.

When in pairs, the electrons - which are fermions with a spin value of 1/2 or -1/2 - act as if they have a spin value of 0, and so do not obey the Pauli exclusion principle. They tend to 'condense' into the lowest energy state, where their wave functions overlap and they act like one large atom or wave - a Bose Einstein condensate.

Cooper pairs are easily broken by thermal energy and so the temperature must be kept low. Bardeen, Cooper, and Schrieffer's theory showed that materials could not become superconductive over about 30 Kelvin (-243.15 °C).

In 1986, however, German physicist Johannes Georg Bednorz and Swiss physicist Karl Alexander Müller discovered superconductivity in a ceramic material at 35 Kelvin (-238.15 °C)[6]. Within a year, superconductivity was shown to occur at 93 Kelvin (-181.15 °C), which meant liquid nitrogen could be used as a coolant[7].

Many other superconductors have since been found at temperatures as high as 138 Kelvin (-135.15 °C)[8]. It's still not understood how pair condensates form in these cases, although they may be created by waves formed by oscillating spin rather than oscillating atoms[9].

Superconducting wires are currently used in a number of modern technologies. They help create the electro-magnets in MRI (Magnetic resonance imaging) scanners[10], and are used to create high speed, magnetically levitated trains, known as Maglev trains[11]. There are currently two Maglev trains in operation, one in South Korea and one in Japan, and they can reach speeds of up to 600 km/h (373 mph)[12].

Superconductivity can occur in protons as well as electrons. Protons are expected to form a superconducting fluid within the crust, and possibly the core, of neutron stars, which are expected to have temperatures of millions of Kelvin[13].

The critical temperature for superconductivity to occur is much higher in this case because protons interact via the strong nuclear force rather than the electromagnetic force[14].

2. Discovery of superfluidity

Superfluidity is a similar effect to superconductivity that was discovered by Canadian physicist John "Jack" Allen and British physicist Don Misener in 1937[15], and was independently discovered by Russian physicist Pyotr Kapitza that same year[16].

Superfluidity allows liquids to flow with zero viscosity, where viscosity is a measure of resistance, analogous to electrical resistance. This allows them to stay completely still even if their container is rotating, flow through pores in their containers, and flow vertically upwards. This occurs because of the siphon effect, which is possible because they still have water tension.

Liquid helium. Credit: Alfred Leitner via ale86itn.

Superfluids are formed in two ways:

  • If the fluid is composed of bosons - like helium-4 - it becomes a real Bose Einstein condensate.

  • If it is composed of fermions - like helium-3 or neutrons - then it can imitate a Bose Einstein condensate.

A superfluid composed of fermions imitates a Bose Einstein condensate in the same way that electrons imitate bosons when the exhibit the effects of superconductivity.

In superfluidity however, the pairs can be formed from neutral atoms or particles, and the interaction is mediated by waves caused by oscillating spin.

Superfluidity can occur at higher temperatures in fluids made of bosons, but the superfluid state is destroyed if the fluid moves over a certain critical velocity.

Superfluidity is also thought to exist inside neutron stars.

3. References

  1. Kamerlingh Onnes, H., 1911, 'Further experiments with liquid helium', Proceedings of the Koninklijke Akademie van Wetenschappen te Amsterdam, 14, pp.113-115.

  2. Meissner, W. and Ochsenfeld, R., 1933, 'Ein neuer effekt bei eintritt der supraleitfähigkeit' ('A new effect when entering the superconductivity'), Naturwissenschaften, 21, pp.787-788.

  3. Bardeen, J., Cooper, L. N. and Schrieffer, J. R., 1957, 'Microscopic theory of superconductivity', Physical Review, 106, pp.162-164.

  4. Bardeen, J., Cooper, L. N. and Schrieffer, J. R., 1957, 'Theory of superconductivity', Physical Review, 108, pp.1175-1204.

  5. Cooper, L. N., 1956, 'Bound electron pairs in a degenerate Fermi gas', Physical Review, 104, pp.1189-1190.

  6. Bednorz, J. G. and Müller, K. A., 1986, 'Possible high T c superconductivity in the Ba—La—Cu—O system', Zeitschrift für Physik B Condensed Matter, 64, pp.189-193.

  7. Wu, M. K., et al, 1987, 'Superconductivity at 93 K in a new mixed-phase Y-Ba-Cu-O compound system at ambient pressure', Physical Review Letters, 58, pp.908-910.

  8. Dai, P., et al, 1995, 'Synthesis and neutron powder diffraction study of the superconductor HgBa2Ca2Cu3O8+delta by Tl substitution', Physica C, 243, pp.201–206.

  9. Radovan, H. A., et al, 2003, 'Magnetic enhancement of superconductivity from electron spin domains', Nature, 425, pp.51-55.

  10. Filippi, M., de Stefano, N., Dousset, V., 2005, 'MR Imaging in White Matter Diseases of the Brain and Spinal Cord', Springer Science & Business Media.

  11. Liu, Z., Long, Z., Li, X., 2015, 'Maglev Trains: Key Underlying Technologies', Springer.

  12. McCurry, J., 2015, 'Japan's maglev train breaks world speed record with 600km/h test run', The Guardian, last accessed 01-06-17.

  13. Shternin, P. S., et al, 2011, 'Cooling neutron star in the Cassiopeia A supernova remnant: evidence for superfluidity in the core', Monthly Notices of the Royal Astronomical Society: Letters, 412, pp.108-112.

  14. Cartlidge, E., 2011, 'Neutron star has superfluid core', Physics World, last accessed 01-06-17.

  15. Allen, J. F. and Misener, A. D., 1938, 'Flow of liquid helium II', Nature, 141, pp.75.

  16. Kapitza, P., 1938, 'Viscosity of liquid helium below the l-point', Nature, 141, pp.74-75.

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The Star Garden is a science news and science education website run by Dr Helen Klus.

How we came to know the cosmos covers the history of physics focusing on space and time, light and matter, and the mind. It explains the simple discoveries we made in prehistoric times, and how we built on them, little by little, until the conclusions of modern theories seem inevitable. This is shown in a timeline of the universe.

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Pre 20th Century theories

1. Atoms and Waves

2. Reflection, Refraction, and Diffraction

3. Newton's theory of Light

4. Measuring the Speed of Light

5. 19th Century Wave Theories

6. 19th Century Particle Theories

7. Spectral Lines and Spectroscopy

Quantum Mechanics

1. Origin of Quantum Mechanics

2. Development of Atomic theory

3. Quantum Mechanical model

4. Sommerfeld's model

5. History of Quantum Spin

6. Superconductivity

7. History of Nuclear Physics

8. De Broglie's Matter Waves

9. Heisenberg's Uncertainty Principle

10. Schrödinger's Wave Equation

11. Quantum Entanglement

12. Schrödinger's Cat

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1. Field Concept in Physics

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3. Strong Nuclear Force

4. Weak Nuclear Force

5. Quantum Gravity